Manchester United will face Barcelona in their Europa League play-off in February, while Jose Mourinho's Roma will take on RB Salzburg.
Barcelona were knocked out of the Champions League before kicking a ball on Wednesday as Inter Milan's 4-0 win over Plzen left them with only a Europa League place.
Napoli thrashed Ajax in their Champions League meeting on Tuesday, with Barcelona and Atletico Madrid both suffering defeats.
Keep up-to-date with all the latest scores from Tuesday's Champions League matches, including Inter Milan vs Barcelona and Ajax vs Napoli...
Bayern Munich cruised past Bayer Leverkusen 4-0 to end a four-game winless run in the Bundesliga and climb into second place.
It was an unhappy return to Munich for Barca striker Robert Lewandowski, the Bavarians' second-highest all-time scorer, who left under a cloud in the summer.
Robert Lewandowski scored a hat-trick as Barcelona opened their Champions League campaign with a comfortable 5-1 win over Viktoria Plzen at the Nou Camp.
Bayer Leverkusen have agreed a season-long loan deal with Chelsea for winger Callum Hudson-Odoi.
Borussia Dortmund began their Bundesliga campaign with a 1-0 win over Bayer Leverkusen at the Signal Iduna Park.
Borussia Dortmund beat Bayer Leverkusen 1-0 in their Bundesliga opener on Saturday but their winning start was overshadowed by an injury to new signing Karim Adeyemi.
Newcastle United retain an interest in Bayer Leverkusen winger Moussa Diaby.
Karim Benzema's last-gasp winner sealed Real Madrid's stunning comeback as they recovered from 2-0 down to beat Sevilla 3-2.
Brazil legend Ze Roberto tells Sky Sports the secrets of extending his career until the age of 43 and explains why he doubts Cristiano Ronaldo will do the same.
Tammy Abraham's penalty more than nine minutes into stoppage time ended Roma’s winless run as Jose Mourinho's scraped a 1-0 victory at 10-man Spezia in Serie A.
Karim Benzema's 83rd-minute goal was enough for Real Madrid to extend their lead at the top of La Liga to nine points with a 1-0 win at Rayo Vallecano.
Juventus' faint Serie A title hopes were further dented by local rivals Torino, who fought their way back to earn a deserved 1-1 draw in Friday night's Turin derby.
Pierre-Emerick Aubameyang made a winning start to his Barcelona career as his new side beat Atletico Madrid 4-2 to move into La Liga's top four.
The Copa del Rey derby match between Real Betis and Sevilla was suspended after a pole hurled from the stands hit Sevilla player Joan Jordan in the head on Saturday.
Borussia Dortmund fought back from two goals down after a lacklustre start to beat Eintracht Frankfurt 3-2 and return some excitement to the Bundesliga title race.
Erling Haaland scored twice as Borussia Dortmund closed the gap on Bundesliga leaders Bayern Munich with a 3-0 win over Greuther Furth at Signal Iduna Park.